O hydrogen bond helps to establish the molecular conformation.
The P atom is in a distorted tetrahedral environment. Geometric parameters are in normal ranges.
Intramolecular hydrogen bonding is observed between the carbonyl group and the hydroxy group.
The N and C atoms of the cation, together with their attached H atoms, lie on the same mirror plane.
The carboxylate group is oriented almost coplanar with the indolizine unit.
O short-contact interactions. O hydrogen bond helps to establish the molecular conformation. S hydrogen bond stabilizes the molecular structure. The bond lengths within the system indicate some degree of delocalization. O hydrogen bonds link molecules into one-dimensional chains along the b-axis direction.
O hydrogen-bond acceptor to the amide and amine groups of two adjacent molecules, resulting in a layered structure. The six-membered rings have chair conformations, while the conformation of the five-membered ring is an envelope. The ethoxybenzene and chlorophenyl rings are located on the same side of the heterocyclic system, resembling the two front claws of a crab. S intermolecular hydrogen bonds, forming a two-dimensional network.
O hydrogen bonds, forming a network. An intramolecular hydrogen bond links the NH group to an O atom of the nearest nitro group.
The molecules are stacked along the b axis. O hydrogen bonds that form centrosymmetric dimers. O intermolecular hydrogen bonds.
S intermolecular interactions.
The bond lengths within the system indicate some degree of delocalization. The bond lengths within the system indicate some degree of delocalization.
O intermolecular hydrogen bonds. The P atom is in a distorted tetrahedral environment.
The latter links molecules into infinite chains.
The structure comprises two molecules in the asymmetric unit, which differ in terms of the orientation of their pendant n-propyl groups.
The N and C atoms of the cation, together with their attached H atoms, lie on the same mirror plane.
S hydrogen bond stabilizes the molecular structure. O hydrogen bonds link the molecules into chains running along the a axis. The structure comprises two molecules in the asymmetric unit, which differ in terms of the orientation of their pendant n-propyl groups.